The following freely-available book is a very good introduction to the world of vocabularies and linked data:
Tom Heath and Christian Bizer (2011) Linked Data: Evolving the Web into a Global Data Space (1st edition). Synthesis Lectures on the Semantic Web: Theory and Technology, 1:1, 1-136. Morgan & Claypool.
Available at: http://linkeddatabook.com/
"This book gives an overview of the principles of Linked Data as well as the Web of Data that has emerged through the application of these principles. The book discusses patterns for publishing Linked Data, describes deployed Linked Data applications and examines their architecture."
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